康 · 学术 | Reaction of the Day No. 1372
Rajender Nallagonda,* Rachel Quan, Lauren Grant, ChristineJorge, Shiuhang Yip, Dauh-Rurng Wu,T. G. Murali Dhar, James Kempson,Arvi
学术 reaction diastereoselectivi 2024-12-26 18:01 2
Rajender Nallagonda,* Rachel Quan, Lauren Grant, ChristineJorge, Shiuhang Yip, Dauh-Rurng Wu,T. G. Murali Dhar, James Kempson,Arvi
学术 reaction diastereoselectivi 2024-12-26 18:01 2
Chemical Development, AstraZeneca, SilkRoad Business Park, SK10 2NA Macclesfield, UK;
北京大学化学学院余志祥课题组一直从事成环反应的发现/应用/机理研究。他的课题组原计划利用一价金阳离子催化剂来将II型二烯-炔烯转化为三环[4.4.1]骨架。实验没有得到预期的产物,而是得到了饱和的二氢半瞬烯衍生物,结构如图所示。该反应机理比较复杂,涉及五个基元
Department of Chemistry MassachusettsInstitute of Technology, New Jersey 08543, United States
学术 reaction activation 2024-12-23 18:02 1
Chemical Process Development, BristolMyers Squibb, New Brunswick, New Jersey 08901, United States; [b] ChemicalProcess Development
KEYWORDS:skeletalediting (反应类型),nitrogen deletion (反应类型), amines (原料), DPPH (试剂), C(sp3)–C(sp3) (成键类型);
The GSK Carbon Neutral Laboratories forSustainable Chemistry, University of Nottingham, Nottingham NG7 2TU, UnitedKingdom;
Monica Oliva,aSerena Pillitteri,aJohannes Schörgenhumer,bRiku SaitocErikV. Van der Eycken,a,dandUpendra K. Sharmaa,e,*
Áron Péter,1†Jiawei Sun,1†Jiayan He,1§JetTsien,1§Haoxiang Zhang,1§BenjaminP. Vokits,2David S. Peters,3Michael D. Mandler,4Maximili
Chakreshwara Kuloor[a], Akash[a], VishakhaGoyal[a, b],Radek Zbořil[b,c]*,Mathias Beller[a]*, Rajenahally V. Jagadeesh[a, b]*
Xuefeng Jiang − Shanghai Key Laboratoryof Green Chemistry and Chemical Processes, State Key Laboratory of PetroleumMolecular & Pro
Otome E. Okoromoba,[a]Ting-An Chen,[a,b]Eun Sil Jang,[a]Claire L. McMullin,[c]Thomas R. Cundari,[d]*and Timothy H. Warren[a,b]*
Merck Center for Catalysis at PrincetonUniversity, Princeton, New Jersey 08544, United States
Merck Center for Catalysis at PrincetonUniversity, Princeton, New Jersey 08544, United States
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KEYWORDS:dechlorination,copper catalysis (反应类型), C(sp3)–H (成键类型), alkyl chloride (原料), C(sp3)–Cl (断键类型), DIBAL-H (其他), IPrCuCl(催化剂
KEYWORDS:Crosselectrophile coupling (XEC) (反应类型),phosphonium salt (原料),alkyl halide (原料), C(sp3)–C(sp3) (成键类型), LiHMDS(试剂), C(sp3)
KEYWORDS:Crosselectrophile coupling (XEC) (反应类型),phosphonium salt (原料),alkyl halide (原料), C(sp3)–C(sp3) (成键类型), LiHMDS(试剂), C(sp3)
StoichiometryDependence in the Consecutive, Competing Reduction, Halogenation,or Deoxygenation of Aryl Carbonyls
Department of Chemistry and ChemicalBiology, Cornell University, Ithaca, New York 14853, United States;